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Literature citations

Unraveling the fungal strategy for tetrahydroxanthone biosynthesis and diversification.

In vivo and in vitro reconstitution of the biosynthesis of fungal tetrahydroxanthones (THXs), blennolides A and C, led to the identification and characterization of the key enzymes for THX biosynthesis and diversification. The unusual isomerase NsrQ plays a crucial role in the THX skeleton synthesis probably by catalyzing the 1,2-hydride shift and methyl group epimerization, thus allowing dearomatizing cyclization to provide the THX architecture.

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